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One can make a homemade insecticide by crushing the leaves and soaking them and then spraying affected plants with the mixture

The only way to completely and permanently eliminate smoke or cigarette smell is to have the affected surfaces professionally cleaned to remove and neutralize those embedded smoke particles and other residue

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Rather than it being easy for the nicotine to get into the blood, it may be the much higher nicotine concentrations in the lungs creates a very steep diffusion gradient that encourages the nicotine to move from the high concentration in the lungs to the much lower concentration in the blood